29 October 2017 to 3 November 2017
Australia/Sydney timezone

Pyrolysis and Plasma applied to Nuclear ion Exchange Resins Treatment

2 Nov 2017, 09:30
15m
Oral Presentation National and international collaborative waste management programs Partitioning & Transmutation

Speaker

Dr hugo luis bianchi (Gerencia Química, Comisión Nacional de Energía Atómica, CAC, Av. Gral. Paz 1499 (1650) Buenos Aires, Argentina / ECyT, UNSAM, Martín de Irigoyen 3100 (1650) San Martín, Argentina)

Description

Spent ion exchange resins (IER) represent an important waste stream that is generated during the operation of both light and heavy-water reactors. Over the past 60 years of nuclear activity Argentina has accumulated over 300 m3 of spent IERs that to this day remain interim storage. With a view toward achieving a significant volume reduction and improved product stability we are investigating a two-step process involving initial low-temperature (< 350 oC) pyrolysis followed by immobilization in a polymeric matrix such as Epoxy or Phenol formaldehyde and nanocomposites thereof without any significant volume increase. Also contemplated as part of the overall process is the destruction of radioactive off-gas using an induction plasma system with subsequent trapping of radioactive gases using high performance adsorbents. This talk will provide an overview of the overall process that is being investigated paying particular attention to the waste form structure and efficient off-gas treatment system.

Primary authors

Dr hugo luis bianchi (Gerencia Química, Comisión Nacional de Energía Atómica, CAC, Av. Gral. Paz 1499 (1650) Buenos Aires, Argentina / ECyT, UNSAM, Martín de Irigoyen 3100 (1650) San Martín, Argentina) Dr vittorio luca (PNGRR, CNEA, CAC, Av. General Paz 1499 (1650) Buenos Aires, Argentina)

Co-authors

Mr hernan ariel castro (PNGRR, CNEA, CAC, Av. General Paz 1499 (1650) Buenos Aires, Argentina / ECyT, UNSAM, Martín de Irigoyen 3100 (1650) San Martín, Argentina) Mr raul ariel rodriguez (Gerencia Química, Comisión Nacional de Energía Atómica, CAC, Av. Gral. Paz 1499 (1650) Buenos Aires, Argentina)

Presentation Materials

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