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SUMMARY:Using Flexible MOFs to Study Inorganic Reactivity
DTSTART;VALUE=DATE-TIME:20141121T012500Z
DTEND;VALUE=DATE-TIME:20141121T014500Z
DTSTAMP;VALUE=DATE-TIME:20260419T081736Z
UID:indico-contribution-716@events01.synchrotron.org.au
DESCRIPTION:Speakers: Chris Sumby (University of Adelaide)\nMetal-organic 
 frameworks (MOFs) are crystalline materials that can be synthesised from m
 etal ions or metal-oxide clusters (nodes) and organic building blocks (lin
 ks).[1]  Through careful consideration of the chemistry of the organic lin
 ks the properties of these materials can be tailored for particular applic
 ations. For example\, a flexible framework capable of high yielding post-s
 ynthetic metallation[2] can be synthesised.[3]  Remarkably\, this material
  (MnMOF) is able to provide structural insight into inorganic reactivity t
 hrough single crystal X-ray crystallography (SCXRD).[3]\n\nThis presentati
 on will describe the structure of this new 3D MOF\, which possesses pore c
 avities that are lined with vacant di-pyrazole groups poised for post-synt
 hetic metallation. As part of this I will illustrate the potential of this
  platform MOF to provide fundamental insight into metal-catalysed reaction
 s in porous solids. For example\, SCXRD studies undertaken partly at the A
 ustralian Synchrotron\, reveal the reaction products of consecutive oxidat
 ive addition and methyl migration steps that occur within the pores of a R
 h metallated example\, MnMOF-[Rh(CO)2][Rh(CO)2Cl2]. \n\n[1] H. Furukawa\, 
 K.E. Cordova\, M. O'Keeffe and O.M. Yaghi\, Science\, 2013\, 341\, 974. \n
 [2] J.D. Evans\, C.J. Sumby and C.J. Doonan\, Chem. Soc. Rev.\, 2014\, 43\
 , 5933-5951.\n[3] W.M. Bloch\, A. Burgun\, C.J. Coghlan\, R. Lee\, M.L. Co
 ote\, C.J. Doonan\, and C.J. Sumby\, Nat. Chem.\, 2014\, doi:10.1038/nchem
 .2045.\n\nhttps://events01.synchrotron.org.au/event/3/contributions/716/
LOCATION: NCSS Seminar Room
URL:https://events01.synchrotron.org.au/event/3/contributions/716/
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