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SUMMARY:Chiral CPs formed using chiral heterotopic ligands
DTSTART;VALUE=DATE-TIME:20211125T072100Z
DTEND;VALUE=DATE-TIME:20211125T072200Z
DTSTAMP;VALUE=DATE-TIME:20260718T054854Z
UID:indico-contribution-4183@events01.synchrotron.org.au
DESCRIPTION:Speakers: Nicholas Kyratzis (Monash University)\nThe use of he
 terotopic ligands in the synthesis of coordination polymers (CPs) using py
 ridyl groups and carboxylates have been extensive.  But the use of chiral 
 heterotopic ligands using pyridyl groups and phthalimide groups has not be
 en explored.  Chiral coordination polymers have been formed using leucine\
 , phenylalanine and cysteine substituted pyridylphthalimide cores (L3pyph\
 , M3pyph and L4pyph)\, where the pyridyl groups have been substituted in t
 he 3 and 4 positions.  One dimensional coordination polymers have been for
 med using L3pyph and P3pyph\, where there are π-π interactions between p
 arallel 1D chains. However\, the use of more exotic amino acids such cyste
 ine\, C3pyph\, has allowed for a 2D coordination polymer to be formed thro
 ugh the formation of disulphide bonds between 1D chains.  A two fold inter
 penetrated 2D dimensional coordination polymer has been formed using L4pyp
 h and P4pyph.  These illustrates that the substitution of the pyridyl grou
 p between the 3 and the 4 position has a major influence with the coordina
 tion polymers formed.\n\nhttps://events01.synchrotron.org.au/event/146/con
 tributions/4183/
LOCATION:Online
URL:https://events01.synchrotron.org.au/event/146/contributions/4183/
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